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- W1845365220 abstract "Publisher Summary This chapter discusses the formation and the properties of Lewis acid sites (LAS) in the zeolite H-MOR by means of electron spin resonance (ESR) spectroscopy through the observation of the radical cation formed upon the adsorption of 2,5-dimethylhexa-l,5-diene (DMHD). The facts established include (1) LAS, which bind ammonia are not the sites, which are responsible for the formation of radical cations, (2) the amount of DMHD + formed is directly related to the partial pressure of molecular oxygen present in the system, and (3) the addition of oxygen to H-mordenite containing DMHD +· leads to a superoxide radical anion.There is strong evidence for a catalytic process involving DMHD + as a radical intermediate in the oxidation of DMHD." @default.
- W1845365220 created "2016-06-24" @default.
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- W1845365220 date "2001-01-01" @default.
- W1845365220 modified "2023-09-26" @default.
- W1845365220 title "13-P-08-ESR investigations of the catalytic properties of lewis acid sites in H-mordenite" @default.
- W1845365220 doi "https://doi.org/10.1016/s0167-2991(01)81787-0" @default.
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