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- W1845393089 abstract "The reaction of EuI2(THF)2 with 3 equiv. of the recently discovered lithium-cyclopropylethinylamidinate Li[c-C3H5–C≡C–C(NCy)2] (1) (Cy = cyclohexyl) unexpectedly afforded the heterometallic europium(III) amidinate complex [{c-C3H5–C≡C–C(NCy)2}Li{c-C3H5–C≡C–C(NCy)2}2Eu(μ-I)2Li(THF)2] (2) in the form of bright yellow, air- and moisture-sensitive crystals. An X-ray diffraction study of 2 revealed several unusual structural features. It comprises a double “ate” complex of the tentative trivalent europium(III) bis(cyclopropylethinylamidinate) derivative [c-C3H5–C≡C–C(NCy)2]2EuIIII. “Ate” complex formation occurred not only through retention of one equiv. of lithium iodide but also through addition of one equiv. of Li[c-C3H5–C≡C–C(NCy)2]. The Li atom in the iodo-bridged Eu(μ-I)2Li(THF)2 part of the molecule is tetrahedrally coordinated, whereas the second lithium atom is only tricoordinate through the presence of a rare monodentate (dangling) amidinate ligand." @default.
- W1845393089 created "2016-06-24" @default.
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- W1845393089 date "2015-06-01" @default.
- W1845393089 modified "2023-10-16" @default.
- W1845393089 title "Synthesis and Structural Characterization of an Unusual Heterometallic Europium(III) Amidinate Complex" @default.
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- W1845393089 doi "https://doi.org/10.1002/zaac.201500200" @default.
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