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• W1845965179 abstract "Macroporous SnO2 (mp-SnO2(P-n); P means polymethylmethacrylate (PMMA) and n = diameter of PMMA microsphere) thick film gas sensors were fabricated by a modified sol-gel method by employing PMMA microspheres (n = 800, 400, 250 and 150 nm) as a template and SnCl2 as a tin source. Morphology of mp-SnO2 films was markedly dependent on the SnCl2 concentration and the diameter of PMMA microspheres. Especially, the ratio of the thickness of the SnO2 wall to the diameter of the hollow SnO2 microsphere seems to increase with decreasing the diameter of PMMA microspheres used. Among the films prepared, mp-SnO2(P-250) exhibited the largest response to NO and NO2 in air at 225 °C, whereas its response transients were relatively slow, indicating low adsorption and desorption speeds of negatively charged chemisorbed NOx species on the SnO2 surface. On the other hand, mp-SnO2(P-800) showed the largest H2 response among the sensors at temperatures higher than 400 °C. It has been revealed that the thickness and porous structure of the SnO2 thick films are important factors to determine the sensing properties to NO2 and H2." @default.
• W1845965179 created "2016-06-24" @default.
• W1845965179 date "2005-05-13" @default.
• W1845965179 modified "2023-09-30" @default.
• W1845965179 title "Preparation of macroporous SnO films using PMMA microspheres and their sensing properties to NO and H" @default.
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• W1845965179 doi "https://doi.org/10.1016/j.snb.2004.07.024" @default.
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