Matches in SemOpenAlex for { <https://semopenalex.org/work/W1849097852> ?p ?o ?g. }
- W1849097852 endingPage "3227" @default.
- W1849097852 startingPage "3220" @default.
- W1849097852 abstract "The use of bifunctional phosphonate anions and metal cations that can adopt different co-ordination environments is proposed as a strategy for synthesising porous metal phosphonates. The hydrothermal methods described use phosphonic acids and dialkylphosphonates, which are hydrolysed in situ by the acidic metal solutions, to derive the desired phosphonate anions. A series of isostructural hydroxymethylphosphonates, M(O3PCH2OH) [M = Zn, Co, Cu and Mn], which contain a hexagonal array of cylindrical channels (approximate diameter 5.7 Å), were prepared by reaction of the relevant metal acetate with diethyl hydroxymethylphosphonate. Zn(O3PCH2C(O)NH2)·H2O was prepared by reaction of zinc acetate and diethyl cyanomethylphosphonate. The structure was determined by single crystal X-ray diffraction and contains two orthogonal channel systems with water molecules situated at the intersections of the channels. Zn3(O3PCH2CO2)2·nH2O [n = 3, 4] was prepared by reaction of phosphonoacetic acid and zinc acetate. Single crystal analysis reveals the presence of channels in the [100] direction with a cross-section of 10.02 × 6.78 Å. All three of the Zn-based materials can be isomorphously doped with Co." @default.
- W1849097852 created "2016-06-24" @default.
- W1849097852 creator A5014732121 @default.
- W1849097852 creator A5018312023 @default.
- W1849097852 creator A5023877785 @default.
- W1849097852 creator A5028274069 @default.
- W1849097852 creator A5084888196 @default.
- W1849097852 date "2002-01-01" @default.
- W1849097852 modified "2023-10-03" @default.
- W1849097852 title "Strategies for the synthesis of porous metal phosphonate materials" @default.
- W1849097852 cites W1600530500 @default.
- W1849097852 cites W1909953063 @default.
- W1849097852 cites W1967022216 @default.
- W1849097852 cites W1972783766 @default.
- W1849097852 cites W1974626287 @default.
- W1849097852 cites W1977037415 @default.
- W1849097852 cites W1980004363 @default.
- W1849097852 cites W1983848736 @default.
- W1849097852 cites W1985647364 @default.
- W1849097852 cites W1989839189 @default.
- W1849097852 cites W1992251285 @default.
- W1849097852 cites W1993397571 @default.
- W1849097852 cites W2004102396 @default.
- W1849097852 cites W2006953578 @default.
- W1849097852 cites W2009845070 @default.
- W1849097852 cites W2016577149 @default.
- W1849097852 cites W2016795611 @default.
- W1849097852 cites W2028812953 @default.
- W1849097852 cites W2031953835 @default.
- W1849097852 cites W2047123460 @default.
- W1849097852 cites W2047373998 @default.
- W1849097852 cites W2049023193 @default.
- W1849097852 cites W2051125035 @default.
- W1849097852 cites W2054601456 @default.
- W1849097852 cites W2057751518 @default.
- W1849097852 cites W2058865357 @default.
- W1849097852 cites W2060210312 @default.
- W1849097852 cites W2060517225 @default.
- W1849097852 cites W2061495132 @default.
- W1849097852 cites W2065749440 @default.
- W1849097852 cites W2069919428 @default.
- W1849097852 cites W2073188845 @default.
- W1849097852 cites W2079172657 @default.
- W1849097852 cites W2079658289 @default.
- W1849097852 cites W2080941157 @default.
- W1849097852 cites W2086998158 @default.
- W1849097852 cites W2141540111 @default.
- W1849097852 cites W2146044109 @default.
- W1849097852 cites W2148902131 @default.
- W1849097852 cites W2157198197 @default.
- W1849097852 cites W2186373767 @default.
- W1849097852 cites W2317128795 @default.
- W1849097852 cites W2949730272 @default.
- W1849097852 cites W3138447739 @default.
- W1849097852 doi "https://doi.org/10.1039/b204131f" @default.
- W1849097852 hasPublicationYear "2002" @default.
- W1849097852 type Work @default.
- W1849097852 sameAs 1849097852 @default.
- W1849097852 citedByCount "52" @default.
- W1849097852 countsByYear W18490978522012 @default.
- W1849097852 countsByYear W18490978522013 @default.
- W1849097852 countsByYear W18490978522014 @default.
- W1849097852 countsByYear W18490978522015 @default.
- W1849097852 countsByYear W18490978522016 @default.
- W1849097852 countsByYear W18490978522017 @default.
- W1849097852 countsByYear W18490978522018 @default.
- W1849097852 countsByYear W18490978522019 @default.
- W1849097852 crossrefType "journal-article" @default.
- W1849097852 hasAuthorship W1849097852A5014732121 @default.
- W1849097852 hasAuthorship W1849097852A5018312023 @default.
- W1849097852 hasAuthorship W1849097852A5023877785 @default.
- W1849097852 hasAuthorship W1849097852A5028274069 @default.
- W1849097852 hasAuthorship W1849097852A5084888196 @default.
- W1849097852 hasConcept C115624301 @default.
- W1849097852 hasConcept C161790260 @default.
- W1849097852 hasConcept C178790620 @default.
- W1849097852 hasConcept C179104552 @default.
- W1849097852 hasConcept C185592680 @default.
- W1849097852 hasConcept C205188671 @default.
- W1849097852 hasConcept C2777626080 @default.
- W1849097852 hasConcept C2780443040 @default.
- W1849097852 hasConcept C32909587 @default.
- W1849097852 hasConcept C535196362 @default.
- W1849097852 hasConcept C544153396 @default.
- W1849097852 hasConcept C8010536 @default.
- W1849097852 hasConcept C94412978 @default.
- W1849097852 hasConceptScore W1849097852C115624301 @default.
- W1849097852 hasConceptScore W1849097852C161790260 @default.
- W1849097852 hasConceptScore W1849097852C178790620 @default.
- W1849097852 hasConceptScore W1849097852C179104552 @default.
- W1849097852 hasConceptScore W1849097852C185592680 @default.
- W1849097852 hasConceptScore W1849097852C205188671 @default.
- W1849097852 hasConceptScore W1849097852C2777626080 @default.
- W1849097852 hasConceptScore W1849097852C2780443040 @default.
- W1849097852 hasConceptScore W1849097852C32909587 @default.
- W1849097852 hasConceptScore W1849097852C535196362 @default.
- W1849097852 hasConceptScore W1849097852C544153396 @default.
- W1849097852 hasConceptScore W1849097852C8010536 @default.