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- W1850765582 abstract "Abstract Six conjugated platinum(II) acetylides with multibranched donor‐acceptor structures ( 1 – 6 ) were synthesized. The absorption maxima of triazine‐centered complexes 1 – 3 are red‐shifted by 36–43 nm compared with those of triphenylamine‐centered complexes 4 – 6 . The luminescence spectra of 4 – 6 in air‐saturated chloroform showed one fluorescence peak and one phosphorescence peak. However, only one fluorescence peak was detected for 1 – 3 in air‐saturated chloroform. The transient absorption spectra of the compounds indicate the effective intersystem crossing from S 1 to T 1 . The nonlinear optical properties of 1 – 6 in N , N ‐dimethylformamide were studied using open Z‐scan method. The results indicate that complexes 1 and 6 exhibit good nonlinear optical performance. The ratios of the effective nonlinear absorption cross section to ground‐state absorption cross section σ eff / σ 0 of complexes 1 – 6 are in the range of 4–22." @default.
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- W1850765582 date "2014-04-28" @default.
- W1850765582 modified "2023-10-17" @default.
- W1850765582 title "Nonlinear Optical Properties of Conjugated Platinum(II) Acetylides with Multibranched Donor–Acceptor Structures" @default.
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- W1850765582 doi "https://doi.org/10.1002/ejic.201402043" @default.
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