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- W1851542783 abstract "The crystal structures and magnetic behaviours of two water-bridged one-dimensional (1D) cobalt(II) chains with different isomeric naphthoate (na(-)) terminals, [Co(H2O)3(2-na)2]n (1) and {[Co(H2O)3(1-na)2]·2H2O}n (2), were reported to investigate the effect of interchain distance on their magnetic properties. Complex 1 with trans-2-na(-) blocks and dense interchain separation exhibits a metamagnetic transition from antiferromagnetic ordering to a saturated paramagnetic phase. By contrast, complex 2 possessing cis-arranged 1-na(-) spacers and good interchain isolation shows unusual single-chain magnetic behavior under a zero dc field. Thus, completely different interchain packing by isomeric naphthoate ligands governs the ratio of intra- to inter-chain magnetic interactions and further results in different magnetic phenomena, which provide significant magnetostructural information on 1D magnetic systems." @default.
- W1851542783 created "2016-06-24" @default.
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- W1851542783 date "2015-01-01" @default.
- W1851542783 modified "2023-09-27" @default.
- W1851542783 title "Two water-bridged cobalt(<scp>ii</scp>) chains with isomeric naphthoate spacers: from metamagnetic to single-chain magnetic behaviour" @default.
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- W1851542783 doi "https://doi.org/10.1039/c5dt03297k" @default.
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