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- W1852230743 abstract "A new ternary phase with a composition of Al3AuIr has been found in the Al-rich area of the Al-Au-Ir system. Differential thermal analysis indicates a melting point of 990 °C, and single-crystal X-ray diffraction measurements reveal that this ternary phase adopts a Ni2Al3 structure type (space group P3̅m1) with a = 4.2584(5) Å and c = 5.1991(7) Å. This compound is isostructural to the Al3Cu1.5Co0.5 phase also found in the Al-rich part of the Al-Cu-Co ternary diagram. Experimental evidence combined with ab initio calculations point toward an Al3AuIr phase stabilized by a Hume-Rothery mechanism. Quantum chemical calculations indicate two-center and multicenter interactions in the Al3AuIr phase. Layered distribution of two-center interactions separated by regions with four- and five-center bonds suggests a preferential cleavage of the material at puckered planes perpendicular to the [001] direction." @default.
- W1852230743 created "2016-06-24" @default.
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- W1852230743 date "2015-08-04" @default.
- W1852230743 modified "2023-10-16" @default.
- W1852230743 title "Al<sub>3</sub>AuIr: A New Compound in the Al–Au–Ir System" @default.
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- W1852230743 doi "https://doi.org/10.1021/acs.inorgchem.5b00946" @default.
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