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- W185350801 abstract "The use of time-resolved ESR spectroscopy to study the kinetics and mechanism of reaction of radicals formed by pulse radiolysis is described. The method is of particular advantage over optical methods where the exact structure of the radical is in doubt or the optical absorption is weak. These advantages are illustrated by several radical conversions such as from the enol − O 2 CC(OH)=CCO 2 − to − O 2 CC(=O)CHCO − 2 and by studies of the polymerization of H 2 C=CCO − 2 with HCCCO − 2 . In addition, the two isomeric radicals formed by OH addition to p-hydroxybenzoate at the ortho and meta positions have been detected and their differing rates of dehydration and oxidation studied." @default.
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- W185350801 date "1982-01-01" @default.
- W185350801 modified "2023-09-26" @default.
- W185350801 title "THE STUDY OF RADICAL REACTION KINETICS BY TIME-RESOLVED ESR" @default.
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- W185350801 doi "https://doi.org/10.1016/b978-0-08-026220-8.50031-2" @default.
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