FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1855017796> ?p ?o ?g. }

• W1855017796 endingPage "204" @default.
• W1855017796 startingPage "200" @default.
• W1855017796 abstract "Abstract Dilution enthalpies of urea (U) and its four derivatives {biuret (BU), methylurea (MU), 1,1-dimethylurea (1,1-DMU) and 1,3-dimethylurea (1,3-DMU)} in (dimethylformamide (DMF) + water) mixtures of various mole fractions ( x DMF  = 0 to 0.10) at T  = 298.15 K have been determined by isothermal titration calorimetry (ITC). In light of the approach of McMillan–Mayer’s theory, enthalpic pairwise self-interaction coefficients ( h 2 ) of each compound at the corresponding composition ( x DMF ) of mixed solvent (DMF + water) have been calculated. It is found that the h 2 coefficients of each compound are all negative in pure water and increase incrementally with the concentration of DMF in the mixed solvent, following the order h 2 (BU)  h 2 (U)  h 2 (MU)  h 2 (1,1-DMU)  h 2 (1,3-DMU). It is concluded that (1) the addition of co-solvent DMF to solvent water is unfavourable to the pairwise self-interactions of these solutes from the point of view of enthalpy; (2) the substitution of methyl (Me) on N atom of urea enhances the component of hydrophobic interactions during the pairwise self-interactions of these solutes; (3) BU is a more hydrophilic molecule than U, and 1,3-DMU is a more hydrophobic molecule than 1,1-DMU." @default.
• W1855017796 created "2016-06-24" @default.
• W1855017796 creator A5047126228 @default.
• W1855017796 creator A5076943977 @default.
• W1855017796 creator A5077423550 @default.
• W1855017796 creator A5087812098 @default.
• W1855017796 date "2016-02-01" @default.
• W1855017796 modified "2023-10-17" @default.
• W1855017796 title "Enthalpic pairwise self-interactions of urea and its four derivatives in (dimethylformamide + water) mixtures rich in water at T = 298.15 K" @default.
• W1855017796 cites W1696127663 @default.
• W1855017796 cites W1964778879 @default.
• W1855017796 cites W1968189370 @default.
• W1855017796 cites W1968478133 @default.
• W1855017796 cites W1970202979 @default.
• W1855017796 cites W1971847312 @default.
• W1855017796 cites W1973907013 @default.
• W1855017796 cites W1976805425 @default.
• W1855017796 cites W1977029208 @default.
• W1855017796 cites W1984372349 @default.
• W1855017796 cites W1990199855 @default.
• W1855017796 cites W1991158297 @default.
• W1855017796 cites W1993204000 @default.
• W1855017796 cites W1993643459 @default.
• W1855017796 cites W1996035003 @default.
• W1855017796 cites W1997243809 @default.
• W1855017796 cites W1997983640 @default.
• W1855017796 cites W2000195491 @default.
• W1855017796 cites W2004474344 @default.
• W1855017796 cites W2007707496 @default.
• W1855017796 cites W2007720944 @default.
• W1855017796 cites W2009625647 @default.
• W1855017796 cites W2011391406 @default.
• W1855017796 cites W2015070893 @default.
• W1855017796 cites W2018871650 @default.
• W1855017796 cites W2020528273 @default.
• W1855017796 cites W2021341954 @default.
• W1855017796 cites W2023712263 @default.
• W1855017796 cites W2025099356 @default.
• W1855017796 cites W2025160349 @default.
• W1855017796 cites W2026076675 @default.
• W1855017796 cites W2027224584 @default.
• W1855017796 cites W2029133507 @default.
• W1855017796 cites W2030054590 @default.
• W1855017796 cites W2032094058 @default.
• W1855017796 cites W2034705454 @default.
• W1855017796 cites W2037334949 @default.
• W1855017796 cites W2037846302 @default.
• W1855017796 cites W2038157915 @default.
• W1855017796 cites W2038731828 @default.
• W1855017796 cites W2044037422 @default.
• W1855017796 cites W2045635725 @default.
• W1855017796 cites W2054494945 @default.
• W1855017796 cites W2067816195 @default.
• W1855017796 cites W2073240417 @default.
• W1855017796 cites W2075867429 @default.
• W1855017796 cites W2076032900 @default.
• W1855017796 cites W2079135205 @default.
• W1855017796 cites W2095451817 @default.
• W1855017796 cites W2120402116 @default.
• W1855017796 cites W2124591043 @default.
• W1855017796 cites W2127348442 @default.
• W1855017796 cites W2130856867 @default.
• W1855017796 cites W2134693697 @default.
• W1855017796 cites W2155828131 @default.
• W1855017796 cites W2170586576 @default.
• W1855017796 cites W2310557223 @default.
• W1855017796 cites W2321769014 @default.
• W1855017796 cites W2321944123 @default.
• W1855017796 cites W2323506473 @default.
• W1855017796 cites W2324828071 @default.
• W1855017796 cites W2326267091 @default.
• W1855017796 cites W2328439354 @default.
• W1855017796 cites W2329676751 @default.
• W1855017796 cites W2950802385 @default.
• W1855017796 cites W4239562459 @default.
• W1855017796 cites W4254737744 @default.
• W1855017796 cites W748553255 @default.
• W1855017796 doi "https://doi.org/10.1016/j.jct.2015.10.010" @default.
• W1855017796 hasPublicationYear "2016" @default.
• W1855017796 type Work @default.
• W1855017796 sameAs 1855017796 @default.
• W1855017796 citedByCount "5" @default.
• W1855017796 countsByYear W18550177962016 @default.
• W1855017796 countsByYear W18550177962017 @default.
• W1855017796 countsByYear W18550177962018 @default.
• W1855017796 countsByYear W18550177962020 @default.
• W1855017796 countsByYear W18550177962021 @default.
• W1855017796 crossrefType "journal-article" @default.
• W1855017796 hasAuthorship W1855017796A5047126228 @default.
• W1855017796 hasAuthorship W1855017796A5076943977 @default.
• W1855017796 hasAuthorship W1855017796A5077423550 @default.
• W1855017796 hasAuthorship W1855017796A5087812098 @default.
• W1855017796 hasConcept C105795698 @default.
• W1855017796 hasConcept C121332964 @default.
• W1855017796 hasConcept C147597530 @default.
• W1855017796 hasConcept C178790620 @default.
• W1855017796 hasConcept C184898388 @default.
• W1855017796 hasConcept C185592680 @default.

• next