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- W185528070 abstract "The importance of conformation of a molecule for its interaction with solid catalysts is discussed. The contributions of conformational enthalpy and entropy are examined. For molecules having a large number of conformations the entropy term can dominate the reaction. Cracking of paraffins on small and medium-pore zeolites is entropy-controlled; a simple molecular sieve effect (shape selectivity) cannot explain the higher reactivity of normal isomers." @default.
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- W185528070 date "1991-01-01" @default.
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- W185528070 title "Conformational Effects in Heterogeneous Catalysis" @default.
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- W185528070 doi "https://doi.org/10.1016/s0167-2991(08)61938-2" @default.
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