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- W185714458 abstract "Information pertinent to the mechanism of carcino- genesis by the hydrocarbons might be elicited if some relationship between biological response and chemical activity could be demonstrated; and therefore any chemical reaction of the hydrocarbons is of interest, regardless of whether any definite biological relation- ship can be shown. One action of the carcinogens which may be of some biological significance is the in- hibition of the oxidation of phospholipids (6, ,o). Other observations regarding possible biochemical re- actions of the hydrocarbons have been made by Fieser (7) and by Boyland (4)- Examination of certain other chemical reactions involving compounds related to the carcinogens might also prove to be of interest. One well-known reaction which easily lends itself to such study is the inhibition of the autoxidation of benzaldehyde by anthracene (I, 2, 5, 9) and other chemicals (3, 8, i3, i4, i5). The inhibiting effect of anthracene is a temporary one, involving the induced oxidation of anthracene to anthraquinone (2). Fol- lowing this, the benzaldehyde autoxidizes at the usual rate. Because of the chemical relationship of anthra- cene to the carcinogenic hydrocarbons, it was thought desirable to test the effect of certain carcinogens on this oxidation. Furthermore, the effect of these sub- stances on heptaldehyde was also determined, since it has been shown that this substance has some in- fluence on the growth of certain tumors (i" @default.
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- W185714458 date "1942-06-01" @default.
- W185714458 modified "2023-09-27" @default.
- W185714458 title "Inhibition of the Autoxidation of Aldehydes by Carcinogenic Chemicals and Related Compounds" @default.
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