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- W1857337533 abstract "The Mossbauer spectroscopy offers a unique opportunity for the investigation of the local properties of iron ions which often, like for instance in iron porphyrins, are the reaction centers as well as the charge and energy transport centers which is the essence of all life processes [2, 4]. In particular, the convolution of the dynamical and electronic properties of those biologically active molecules focuses attention of researchers. There have been already performed extension studies on both the solid state and solution studies on the electronic properties of iron porphyrins, what has been summarized in [5, 9, 10]. Silver et al. have presented studies in the aqueous solution of the iron-porphyrin complexes [10]. However, in this paper we attempt to gain some new information on two problems. First one, how variation in the outer ligands of the heme ring in iron-porphyrins influences the strength of the iron. Secondly, how the porphyrin-porphyrin interactions may block the flexibility of the entire molecule. For this purpose, electronic and molecular properties of two selected types of iron porphyrins in a powder form as well as in DMF solutions have been examined and compared." @default.
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- W1857337533 date "2013-01-01" @default.
- W1857337533 modified "2023-10-17" @default.
- W1857337533 title "Inter - and inframolecular dynamics of iron porphyrins" @default.
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