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- W1857995127 abstract "This chapter describes that the use of thermal desorption methods for the study of species adsorbed on surfaces is widespread. The study of thermal desorption supplies useful information to basic science as well as information of importance to technology. The study of thermally activated desorption phenomena represents a natural combination of chemical kinetics, statistical thermodynamics, and molecular dynamics. Knowledge of the nature of the desorption process has fundamental implications to understanding the nature of elementary chemical processes in the layer, to the energetics of bonding and the specification of the chemical nature of the bound species, and to the nature and magnitude of interactional effects between adsorbate species. The chapter discusses that the extension of thermal desorption methods to the study of the interaction of more complex molecules, with surfaces, has now occurred. Studies of desorption kinetics from these systems can suggest the nature of surface-stabilized molecular fragments of importance to a fundamental understanding of catalytic chemistry at surfaces. It concludes that in the future, further refinement in experimental methods for studying desorption processes will be devised, so that thermal desorption may be understood on a more fundamental molecular basis. In addition, continued widespread application to the technological problems is anticipated, particularly to high-area powdered substrates." @default.
- W1857995127 created "2016-06-24" @default.
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- W1857995127 date "1985-01-01" @default.
- W1857995127 modified "2023-09-23" @default.
- W1857995127 title "8. The Thermal Desorption of Adsorbed Species" @default.
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- W1857995127 doi "https://doi.org/10.1016/s0076-695x(08)60322-1" @default.
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