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- W185939605 abstract "Adsorption of metal complexes on carbon supports can be accompanied by ligand-exchange involving intrinsic π-fragments of carbon framework. The size of metal crystallites derived from carbon-adsorbed species does not correlate with the proportion of metal accessible to carbon monoxide and reagents of catalytic reaction; this suggests blocking a part of the metallic surface by walls of the support pores. Appropriate choice of the support, metal precursor and procedures at the deposition step makes it possible to eliminate or, at least, diminish such a detrimental effect and to control the size, shape, sites of location, distribution along the catalyst grain and, thus, catalytic properties of final metal crystallites. A strightforward use of carbon-adsorbed complexes as heterogenized catalysts is also discussed." @default.
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- W185939605 date "1991-01-01" @default.
- W185939605 modified "2023-10-14" @default.
- W185939605 title "Carbon-Supported Palladium Catalysts. Some Aspects of Preparation in Connection with the Adsorption Properties of the Supports" @default.
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- W185939605 doi "https://doi.org/10.1016/s0167-2991(08)64607-8" @default.
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