Matches in SemOpenAlex for { <https://semopenalex.org/work/W185963625> ?p ?o ?g. }
Showing items 1 to 75 of
75
with 100 items per page.
- W185963625 abstract "Studies designed to measure the apparent first order decay of the NO{sub 3} radical are reported here: NO{sub 3} (+M) {yields} NO + O{sub 2} (+M) (R1). Two techniques were employed: (1) direct absorption measurements of (NO{sub 2}) and (NO{sub 3}) were made in the visible in a mixture of N{sub 2}O{sub 5} in nitrogen; and (2) NO{sub 3} was followed indirectly through measured infrared absorptions of NO{sub 2} and N{sub 2}O{sub 5} and calculated from the N{sub 2}O{sub 5} equilibrium relation. Rate data were obtained in experiments over a range of temperatures (313-347 K) and pressures of added N{sub 2} (5-2,000 torr). Rate coefficient data obtained in experiments at P{sub n2} 40 torr show an apparent increase in k{sub 1} with P{sub n2}, and a negative temperature coefficient which is attributed to a wall-catalyzed decomposition of NO{sub 3}, presumably to form NO and O{sub 2} by the stoichiometry of reactionmore » (R1). Although observations on the kinetics of reaction (R1) are only qualitative, they support those of Johnston et al. The occurrence of a first order, homogeneous decomposition of NO{sub 3} in the atmosphere can explain most of Noxon's (1983) observations of NO{sub 3} scavenging in the troposphere. However, his reported loss of NO{sub x} during the nighttime hours requires, in addition, a contribution from some other, unidentified reaction pathway. Alternatives for this removal mechanism are discussed in view of their current knowledge.« less" @default.
- W185963625 created "2016-06-24" @default.
- W185963625 creator A5021414512 @default.
- W185963625 creator A5023254432 @default.
- W185963625 creator A5037448415 @default.
- W185963625 creator A5074467381 @default.
- W185963625 creator A5084451270 @default.
- W185963625 date "1990-08-20" @default.
- W185963625 modified "2023-09-24" @default.
- W185963625 title "The NO sub 3 radical decomposition and NO sub 3 scavenging in the troposphere" @default.
- W185963625 hasPublicationYear "1990" @default.
- W185963625 type Work @default.
- W185963625 sameAs 185963625 @default.
- W185963625 citedByCount "0" @default.
- W185963625 crossrefType "journal-article" @default.
- W185963625 hasAuthorship W185963625A5021414512 @default.
- W185963625 hasAuthorship W185963625A5023254432 @default.
- W185963625 hasAuthorship W185963625A5037448415 @default.
- W185963625 hasAuthorship W185963625A5074467381 @default.
- W185963625 hasAuthorship W185963625A5084451270 @default.
- W185963625 hasConcept C113196181 @default.
- W185963625 hasConcept C119824511 @default.
- W185963625 hasConcept C120665830 @default.
- W185963625 hasConcept C121332964 @default.
- W185963625 hasConcept C124681953 @default.
- W185963625 hasConcept C125287762 @default.
- W185963625 hasConcept C144082473 @default.
- W185963625 hasConcept C147789679 @default.
- W185963625 hasConcept C148898269 @default.
- W185963625 hasConcept C153294291 @default.
- W185963625 hasConcept C158355884 @default.
- W185963625 hasConcept C178790620 @default.
- W185963625 hasConcept C185592680 @default.
- W185963625 hasConcept C2777807096 @default.
- W185963625 hasConcept C2778004101 @default.
- W185963625 hasConcept C30646810 @default.
- W185963625 hasConcept C36663273 @default.
- W185963625 hasConcept C43617362 @default.
- W185963625 hasConcept C55493867 @default.
- W185963625 hasConcept C62520636 @default.
- W185963625 hasConcept C65440619 @default.
- W185963625 hasConcept C9075549 @default.
- W185963625 hasConcept C93391505 @default.
- W185963625 hasConcept C97355855 @default.
- W185963625 hasConceptScore W185963625C113196181 @default.
- W185963625 hasConceptScore W185963625C119824511 @default.
- W185963625 hasConceptScore W185963625C120665830 @default.
- W185963625 hasConceptScore W185963625C121332964 @default.
- W185963625 hasConceptScore W185963625C124681953 @default.
- W185963625 hasConceptScore W185963625C125287762 @default.
- W185963625 hasConceptScore W185963625C144082473 @default.
- W185963625 hasConceptScore W185963625C147789679 @default.
- W185963625 hasConceptScore W185963625C148898269 @default.
- W185963625 hasConceptScore W185963625C153294291 @default.
- W185963625 hasConceptScore W185963625C158355884 @default.
- W185963625 hasConceptScore W185963625C178790620 @default.
- W185963625 hasConceptScore W185963625C185592680 @default.
- W185963625 hasConceptScore W185963625C2777807096 @default.
- W185963625 hasConceptScore W185963625C2778004101 @default.
- W185963625 hasConceptScore W185963625C30646810 @default.
- W185963625 hasConceptScore W185963625C36663273 @default.
- W185963625 hasConceptScore W185963625C43617362 @default.
- W185963625 hasConceptScore W185963625C55493867 @default.
- W185963625 hasConceptScore W185963625C62520636 @default.
- W185963625 hasConceptScore W185963625C65440619 @default.
- W185963625 hasConceptScore W185963625C9075549 @default.
- W185963625 hasConceptScore W185963625C93391505 @default.
- W185963625 hasConceptScore W185963625C97355855 @default.
- W185963625 hasLocation W1859636251 @default.
- W185963625 hasOpenAccess W185963625 @default.
- W185963625 hasPrimaryLocation W1859636251 @default.
- W185963625 isParatext "false" @default.
- W185963625 isRetracted "false" @default.
- W185963625 magId "185963625" @default.
- W185963625 workType "article" @default.