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- W1860672237 endingPage "5994" @default.
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- W1860672237 abstract "A novel type of photocyclization of α-ketoamides was developed, affording unique cyclopropanols bearing amide functionality. N-tert-Butyl, N-trityl, or N-non-substituted α-ketoamides with a bulky substituent at the β-position of the amide functionality were efficiently converted to corresponding cyclopropanols through the activation of the γ-CH bond followed by CC bond formation between the α- and γ-positions of the amide. Hydrogen abstraction from the γ-position of the amide was considered to be the rate-determining step of cyclopropanol formation, based on the kinetic isotope effect. Cyclopropanols could be converted to two different types of functionalized α-ketoamides depending on the method of ring-opening." @default.
- W1860672237 created "2016-06-24" @default.
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- W1860672237 date "2015-10-01" @default.
- W1860672237 modified "2023-09-25" @default.
- W1860672237 title "Photo-induced formation of cyclopropanols from α-ketoamides via γ-CH bond activation" @default.
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- W1860672237 doi "https://doi.org/10.1016/j.tetlet.2015.09.038" @default.
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