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- W1861851237 abstract "From measurements of the absolute concentrations of vibrationally excited oxygen produced in levels v = 4 to v = 13, it is concluded that ca . 20 % of the exothermicity of the reaction O( 3 P) + NO 2 → NO + O + 2 ( v ≤11) (1) appears initially as vibrational energy in oxygen. Vibrationally excited nitric oxide ( v = 1, 2) is also observed and may be produced in this reaction or in the primary process NO 2 + hv → NO ( v ≤ 2) + O( 3 P). More highly excited oxygen ( v ≤ 15), with energy exceeding the exothermicity of the reaction, is produced in reaction (1) when the NO 2 is first excited by radiation above the dissociation limit near 400 nm. The excited NO 2 thus produced can also transfer energy to nitric oxide. NO 2 * + NO( v = 0) → NO 2 + NO( v = 1)." @default.
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- W1861851237 date "1973-09-25" @default.
- W1861851237 modified "2023-09-24" @default.
- W1861851237 title "Energy disequilibrium in the flash photolysis of NO<sub>2</sub>" @default.
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- W1861851237 doi "https://doi.org/10.1098/rspa.1973.0109" @default.
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