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- W1862188401 abstract "The crystal structure of Mg 2 As 2 O 7 has been refined by full matrix least squares procedures using 587 observed reflections. The structure of Mg 2 As 2 O 7 is of the thortveitite type, as reported by Łukaszewicz, with space group C2/m and unit cell dimensions a = 6.567(2) Å, b = 8.524(4) Å, c = 4.739(1) Å, β = 103.8(1)°, and Z = 2. The As—O—As group in the anion appears to be linear but the central oxygen atom undergoes considerable disorder in the plane perpendicular to this group. The AsO bond distances uncorrected for thermal motion are 1.67 Å for the As—O(—As) bond and 1.66 and 1.65 Å for the terminal As—O bonds. The final R value obtained is 0.088." @default.
- W1862188401 created "2016-06-24" @default.
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- W1862188401 date "1970-03-15" @default.
- W1862188401 modified "2023-09-24" @default.
- W1862188401 title "Refinement of the structure of Mg2As2O7" @default.
- W1862188401 doi "https://doi.org/10.1139/v70-146" @default.
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