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- W1862510128 abstract "The thermodynamical properties of poly(dimethylsiloxane) (PDMS) were studied in the theta-solvent styrene. Moderately diluted and semidiluted solutions of three PDMS samples with weight-average molecular weights M̄w = 23 500, 160 000, and 860 000 were investigated by means of light scattering near the theta-temperature. The dependency of the interaction parameter X on temperature and concentration was established for the three samples. The study of the third virial coefficient A3 showed that A3 is independent of molecular weight and temperature as predicted by theory. However, the experimental value of A3/(AM) was higher than expected. The critical properties, i.e., critical point and spinodal, were considered." @default.
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- W1862510128 date "1987-12-01" @default.
- W1862510128 modified "2023-09-26" @default.
- W1862510128 doi "https://doi.org/10.1002/macp.1987.021881214" @default.
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