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• W1863992258 abstract "Abstract The phosphorylating reagent bis [ S ‐(4,4′‐dimethoxytrityl)‐2‐mercaptoethyl]‐ N , N ‐diisopropylphosphoramidite is prepared in three steps from commercial methyl thioglycolate and diisopropylphosphoramidous dichloride. The phosphorylating reagent has been used successfully in the solid‐phase synthesis of deoxyribonucleoside 5′‐/3′‐phosphate or ‐thiophosphate monoesters and oligonucleotide 5′‐phosphate/‐thiophosphate monoesters. Bis [ S ‐(4,4′‐dimethoxytrityl)‐2‐mercaptoethyl]‐ N , N ‐diisopropylphosphoramidite has also been employed in the construction of a thermolytic dinucleotide prodrug model to evaluate the ability of the reagent to produce thermosentive oligonucleotide prodrugs under mild temperature conditions (∼25°C) for potential therapeutic applications." @default.
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• W1863992258 date "2006-09-01" @default.
• W1863992258 modified "2023-09-27" @default.
• W1863992258 title "Chemical Phosphorylation of Deoxyribonucleosides and Thermolytic DNA Oligonucleotides" @default.
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• W1863992258 doi "https://doi.org/10.1002/0471142700.nc1306s26" @default.
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