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- W1867504237 abstract "Two isostructural metal-organic frameworks formulated as [Gd7(L)4(μ3-OH)8(HCOO)(DMF)6(H2O)]·DMF·H2O (1) and [Tb7(L)4(μ3-OH)8(HCOO)(DMF)5(H2O)]·DMF·H2O (2) (H3L=3,5-di(4′-carboxylphenyl)benzoic acid) have been synthesized and structurally characterized. The building blocks of the structures are the heptanuclear lanthanide clusters of the dicubane-like type [Ln7(μ3-OH)8]13+ (Ln=Gd, Tb) which are formally assembled into porous three-dimensional networks through the linkage of L. Variable temperature magnetic studies down to 2 K reveal antiferromagnetic interactions in complex 1. Furthermore, the fluorescence property of 2 was also studied." @default.
- W1867504237 created "2016-06-24" @default.
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- W1867504237 date "2015-10-28" @default.
- W1867504237 modified "2023-09-25" @default.
- W1867504237 title "Synthesis and Characterization of Two Isostructural Lanthanide-Containing Metal-Organic Frameworks Constructed from an Unprecedented [Ln7(μ3-OH)8]13+Cluster" @default.
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- W1867504237 doi "https://doi.org/10.1002/cjoc.201500605" @default.
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