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• W1870117814 abstract "We probe small scalar coupling differences via the coherent interactions between two nuclear spin singlet states in organic molecules. We show that the spin-lock induced crossing (SLIC) technique enables the coherent transfer of singlet order between one spin pair and another. The transfer is mediated by the difference in cis and trans vicinal J couplings among the spins. By measuring the transfer rate, we calculate a J coupling difference of $8 pm 2$ mHz in phenylalanine-glycine-glycine and $2.57 pm 0.04$ Hz in glutamate. We also characterize a coherence between two singlet states in glutamate, which may enable the creation of a long-lived quantum memory." @default.
• W1870117814 created "2016-06-24" @default.
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• W1870117814 date "2016-01-01" @default.
• W1870117814 modified "2023-10-18" @default.
• W1870117814 title "Probing scalar coupling differences via long-lived singlet states" @default.
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• W1870117814 doi "https://doi.org/10.1016/j.jmr.2015.12.003" @default.
• W1870117814 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26717036" @default.
• W1870117814 hasPublicationYear "2016" @default.
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