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• W1874636596 abstract "Abstract In the crystal structure of tris(2 , 2,6,6‐tetramethyl‐3,5‐heptanedionato)mono(bathophenanthroline)erbium(III), C 57 H 73 ErN 2 O 6 , the Er 3+ ion is in an antiprismatic environment, surrounded by two N atoms and six O atoms. The β‐diketonato ligands show structural disorder. The ac susceptibility studies conducted at frequencies from 33 to 9995 Hz and at temperatures from 1.7 to 10 K revealed that the application of a static magnetic field induces a slow magnetic relaxation. Two relaxation modes (fast relaxation = FR; slow relaxation = SR) could be distinguished with energy barriers U FR / k B = 15.6 K and U SR / k B = 22.4 K and relaxation times of 10 –6 and 10 –4 s, respectively. The Er 3+ compound is luminescent in the solid state, emitting in the near IR region." @default.
• W1874636596 created "2016-06-24" @default.
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• W1874636596 date "2013-12-04" @default.
• W1874636596 modified "2023-10-12" @default.
• W1874636596 title "Single‐Ion Magnetism in a Luminescent Er³⁺ β‐Diketonato Complex with Multiple Relaxation Mechanisms" @default.
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• W1874636596 doi "https://doi.org/10.1002/ejic.201301076" @default.
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