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• W187583397 abstract "Cellulose triphenylcarbamate and eighteen mono- or disubstituted derivatives were adsorbed on silica gel and their chiral recognition abilities as stationary phases for high-performance liquid chromatography were investigated. The inductive effect of the substituents greatly influenced the optical resolution ability when they were at the 3- or 4-position. 2-Substituted derivatives showed a low degree of resolution. Among nine 4-substituted phenylcarbamates, the 4-methyl, 4-ethyl, 4-chloro, or 4- trifluoromethyl derivative showed the most efficient chiral recognition for racemic compounds. Dimethylphenyl- and dichlorophenylcarbamates substituted at the 3,4- or 3,5-positions showed better chiral recognition for most enantiomers than the monosubstituted derivatives. Most stationary phases possessed high durability and many racemic compounds were resolved on these phenylcarbamates." @default.
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• W187583397 date "1986-01-01" @default.
• W187583397 modified "2023-10-02" @default.
• W187583397 title "Chromatographic resolution" @default.
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• W187583397 doi "https://doi.org/10.1016/s0021-9673(01)83736-5" @default.
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