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- W1877302297 abstract "Sodium 5-methyl-3,7-octadienoate (2) was synthesized as an amphiphile which contains a double bond at the chain end. The micelle formation behaviour of 2 was examined by measuring the electric conductivity of its aqueous solutions; the pre-critical micelle concentration (pre-CMC) and the genuine critical micelle concentration (CMC) were estimated to be 0,09 and 0,23 mol · 1−1, respectively. Polymerization of 2 under irradiation with UV light was investigated, and it was found that practically no polymer is obtained at concentrations lower than the pre-CMC, while the amount of polymer obtained increases rapidly with increasing concentration of 2 in the polymerization system at concentrations higher than the pre-CMC. The number-average degree of polymerization of poly(2) is about 6. Pre-CMC and CMC of poly(2), which are inferred to correspond to the concentrations to start intra- and intermolecular aggregation, are 1,2 · 10−3 and 9,4 · 10−3 mol · 1−1, respectively. These results are compared with those of sodium 10-undecenoate." @default.
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- W1877302297 date "1990-11-01" @default.
- W1877302297 modified "2023-09-27" @default.
- W1877302297 doi "https://doi.org/10.1002/macp.1990.021911113" @default.
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