Matches in SemOpenAlex for { <https://semopenalex.org/work/W1880134105> ?p ?o ?g. }
- W1880134105 endingPage "451" @default.
- W1880134105 startingPage "442" @default.
- W1880134105 abstract "Abstract Pt/Mo2C is known to have water–gas shift (WGS) rate per total mole of Pt that is higher than on any oxide-supported Pt catalyst. The difficulties for the characterization of Pt/Mo2C were overcome by preparing the carbide using Multi-Walled Carbon Nanotubes (MWCNT), which showed the expected kinetics. X-ray absorption spectroscopy confirmed formation of alloy with Mo and STEM–EELS data confirmed the elemental composition of Pt particles as Pt–Mo for a series of Pt/Mo2C/MWCNT catalysts. A linear correlation is obtained between the WGS rate per gram at 120 °C and the area covered by Pt–Mo alloy nanoparticles on Mo2C, estimated using STEM images. Pt is shown to preferentially bind to the Mo2C domains. The kinetic data in tandem with the characterization techniques suggest that the active sites are formed by Pt–Mo alloy nanoparticles in contact with Mo2C, not by the formation of the alloy. The water activation on Mo2C is suggested to be the cause for the higher WGS rate over Pt/Mo2C." @default.
- W1880134105 created "2016-06-24" @default.
- W1880134105 creator A5010630640 @default.
- W1880134105 creator A5023735477 @default.
- W1880134105 creator A5057812265 @default.
- W1880134105 creator A5073386748 @default.
- W1880134105 creator A5075870873 @default.
- W1880134105 creator A5080850118 @default.
- W1880134105 creator A5087450275 @default.
- W1880134105 creator A5090234803 @default.
- W1880134105 date "2015-10-01" @default.
- W1880134105 modified "2023-10-16" @default.
- W1880134105 title "Probing the active sites for water–gas shift over Pt/molybdenum carbide using multi-walled carbon nanotubes" @default.
- W1880134105 cites W1972514527 @default.
- W1880134105 cites W1976018892 @default.
- W1880134105 cites W1985947461 @default.
- W1880134105 cites W1991795112 @default.
- W1880134105 cites W2004382145 @default.
- W1880134105 cites W2005541811 @default.
- W1880134105 cites W2011865052 @default.
- W1880134105 cites W2035670074 @default.
- W1880134105 cites W2047025465 @default.
- W1880134105 cites W2057353338 @default.
- W1880134105 cites W2070143183 @default.
- W1880134105 cites W2120037314 @default.
- W1880134105 cites W2148076532 @default.
- W1880134105 cites W2321245849 @default.
- W1880134105 cites W2321826431 @default.
- W1880134105 doi "https://doi.org/10.1016/j.jcat.2015.07.032" @default.
- W1880134105 hasPublicationYear "2015" @default.
- W1880134105 type Work @default.
- W1880134105 sameAs 1880134105 @default.
- W1880134105 citedByCount "22" @default.
- W1880134105 countsByYear W18801341052015 @default.
- W1880134105 countsByYear W18801341052016 @default.
- W1880134105 countsByYear W18801341052017 @default.
- W1880134105 countsByYear W18801341052018 @default.
- W1880134105 countsByYear W18801341052019 @default.
- W1880134105 countsByYear W18801341052020 @default.
- W1880134105 countsByYear W18801341052021 @default.
- W1880134105 countsByYear W18801341052022 @default.
- W1880134105 countsByYear W18801341052023 @default.
- W1880134105 crossrefType "journal-article" @default.
- W1880134105 hasAuthorship W1880134105A5010630640 @default.
- W1880134105 hasAuthorship W1880134105A5023735477 @default.
- W1880134105 hasAuthorship W1880134105A5057812265 @default.
- W1880134105 hasAuthorship W1880134105A5073386748 @default.
- W1880134105 hasAuthorship W1880134105A5075870873 @default.
- W1880134105 hasAuthorship W1880134105A5080850118 @default.
- W1880134105 hasAuthorship W1880134105A5087450275 @default.
- W1880134105 hasAuthorship W1880134105A5090234803 @default.
- W1880134105 hasBestOaLocation W18801341051 @default.
- W1880134105 hasConcept C104779481 @default.
- W1880134105 hasConcept C127413603 @default.
- W1880134105 hasConcept C140205800 @default.
- W1880134105 hasConcept C159985019 @default.
- W1880134105 hasConcept C161790260 @default.
- W1880134105 hasConcept C171250308 @default.
- W1880134105 hasConcept C178790620 @default.
- W1880134105 hasConcept C179104552 @default.
- W1880134105 hasConcept C185592680 @default.
- W1880134105 hasConcept C192562407 @default.
- W1880134105 hasConcept C2993655865 @default.
- W1880134105 hasConcept C42360764 @default.
- W1880134105 hasConcept C513720949 @default.
- W1880134105 hasConcept C5335593 @default.
- W1880134105 hasConcept C548081761 @default.
- W1880134105 hasConcept C549387045 @default.
- W1880134105 hasConcept C66114498 @default.
- W1880134105 hasConceptScore W1880134105C104779481 @default.
- W1880134105 hasConceptScore W1880134105C127413603 @default.
- W1880134105 hasConceptScore W1880134105C140205800 @default.
- W1880134105 hasConceptScore W1880134105C159985019 @default.
- W1880134105 hasConceptScore W1880134105C161790260 @default.
- W1880134105 hasConceptScore W1880134105C171250308 @default.
- W1880134105 hasConceptScore W1880134105C178790620 @default.
- W1880134105 hasConceptScore W1880134105C179104552 @default.
- W1880134105 hasConceptScore W1880134105C185592680 @default.
- W1880134105 hasConceptScore W1880134105C192562407 @default.
- W1880134105 hasConceptScore W1880134105C2993655865 @default.
- W1880134105 hasConceptScore W1880134105C42360764 @default.
- W1880134105 hasConceptScore W1880134105C513720949 @default.
- W1880134105 hasConceptScore W1880134105C5335593 @default.
- W1880134105 hasConceptScore W1880134105C548081761 @default.
- W1880134105 hasConceptScore W1880134105C549387045 @default.
- W1880134105 hasConceptScore W1880134105C66114498 @default.
- W1880134105 hasFunder F4320306084 @default.
- W1880134105 hasLocation W18801341051 @default.
- W1880134105 hasLocation W18801341052 @default.
- W1880134105 hasOpenAccess W1880134105 @default.
- W1880134105 hasPrimaryLocation W18801341051 @default.
- W1880134105 hasRelatedWork W1510677920 @default.
- W1880134105 hasRelatedWork W1981913982 @default.
- W1880134105 hasRelatedWork W2006294062 @default.
- W1880134105 hasRelatedWork W2011911312 @default.
- W1880134105 hasRelatedWork W2018523801 @default.
- W1880134105 hasRelatedWork W2057808024 @default.
- W1880134105 hasRelatedWork W2070923073 @default.