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• W1880589621 abstract "Nickel nanoparticles are prepared through thermolysis or polyol procedures and they are fully characterized through TEM and XRD. The catalytic efficiencies are tested toward the hydrogenation reaction of 4-nitrophenol, which was spectrophotometrically detected. A significant improvement of the reaction rate and turnover number (TON) and frequency (TOF) is observed using alkyl amine-stabilized nanoparticles, likely due to their reduced surface steric hindrance. However, the polymer stabilized-nanocatalysts show a better selectivity for product formation, since only hydrogenation products are observed, while azo-benzene derivatives are detected when alkyl amine-stabilized nanoparticles are used. The findings indicate an important impact of surface properties of colloids on the catalysed reaction." @default.
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• W1880589621 date "2016-01-01" @default.
• W1880589621 modified "2023-09-24" @default.
• W1880589621 title "Spectrophotometric analysis of nickel colloid performances as catalysts for hydrogenation of nitro-phenol: Influence of the stabilizing agents" @default.
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• W1880589621 doi "https://doi.org/10.1016/j.catcom.2015.10.036" @default.
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