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- W1882759660 abstract "The thermofor catalytic cracking (TCC) process was developed in the late 1930s and early 1940s, to break down heavy fuel oil into gasoline. The thermofor catalytic cracker is now being replaced by fluid cracking, but the lessons learned from TCC modeling and the confidence gained has not been forgotten. In fluid catalytic cracking and in reforming today, it is possible to describe the events in a reactor quite precisely, based on laboratory and pilot-plant data. This chapter presents one of the early applications of reaction engineering, which was well under way in 1952. The laboratory kinetic experiments are described. The diffusional analysis, the integration of these phenomena into a mathematical process model, its field testing and validation, and subsequent use in process design, modification, control, and optimization are then discussed. The chapter dwells in the kinetic experiments to study the key underlying phenomena of coke burning, independent of other complicating phenomena. The fast coke burns mostly in the gas phase in the kiln. The remaining coke, designated “slow” coke, is not desorbable and burned on the surface of the catalyst. The chapter presents an analytical solution of the kiln equation for slow coke, dynamic response model, and the inclusion of the kinetics of the conversion of CO to CO2 in the model. Finally, the future scope of reaction engineering and essential prerequisites are illustrated." @default.
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- W1882759660 date "1983-01-01" @default.
- W1882759660 modified "2023-10-17" @default.
- W1882759660 title "A Reaction Engineering Case History: Coke Burning in Thermofor Catalytic Cracking Regenerators" @default.
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- W1882759660 doi "https://doi.org/10.1016/s0065-2377(08)60250-1" @default.
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