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• W1884192661 abstract "A series of transition metal coordination complexes, {[Cu(3-Sptta)2]·1/2H2O}n (1), {[Cd(3-Sptta)2]·1/2H2O}n (2), [Zn(3-Sptta)2(H2O)4] (3), and [Co(3-Sptta)2(H2O)4] (4) were synthesized under solvothermal and solvent evaporation conditions using the newly designed heterocyclic N/NS carboxylate ligand [2-(3-pyridyl)-1,3,4-thiadiazole-5-]-thio-acetate (3-Sptta) as a main building block. Their structures were determined by single-crystal X-ray diffraction analyses and further characterized by elemental analyses and IR spectroscopy. The four complexes exhibit structural diversity: complexes 1 and 2 exhibit similar 2D “wave-like” double-layer framework with two shares of mutually parallel left-handed and right-handed helical chains, whereas 3 and 4 present mononuclear structures. Moreover, the thermal stabilities of complexes 1–4 were investigated. The luminescent properties of complexes 2, 3 and the free ligand were also studied." @default.
• W1884192661 created "2016-06-24" @default.
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• W1884192661 date "2015-09-16" @default.
• W1884192661 modified "2023-10-04" @default.
• W1884192661 title "Syntheses, Crystal Structures, Thermal and Photoluminescent Properties of Four Coordination Complexes with a Hetero­cyclic Thioether Carboxylate Ligand" @default.
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• W1884192661 doi "https://doi.org/10.1002/zaac.201500549" @default.
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