FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1884662242> ?p ?o ?g. }

• W1884662242 endingPage "227" @default.
• W1884662242 startingPage "221" @default.
• W1884662242 abstract "Abstract The modulated synthesis of the thienothiophene based zirconium metal–organic framework (MOF) material having formula [Zr6O4(OH)4(DMTDC)6]·4.8DMF·10H2O (1) (H2DMTDC=3,4-dimethylthieno[2,3-b]thiophene-2,5-dicarboxylic acid; DMF=N,N'-dimethylformamide) was carried out by heating a mixture of ZrCl4, H2DMTDC linker and benzoic acid (used as a modulator) with a molar ratio of 1:1:30 in DMF at 150 °C for 24 h. Systematic investigations have been performed in order to realize the effect of ZrCl4/benzoic acid molar ratio on the crystallinity of the material. The activation (i.e., the removal of the guest solvent molecules from the pores) of as-synthesized compound was achieved by stirring it with methanol and subsequently heating under vacuum. A combination of X-ray diffraction (XRD), Fourier transform infrared (FT-IR), thermogravimetric (TG) and elemental analysis was used to examine the phase purity of the as-synthesized and thermally activated 1. The material displays high thermal stability up to 310 °C in an air atmosphere. As revealed from the XRD measurements, the compound retains its crystallinity when treated with water, acetic acid and 1 M HCl solutions. The N2 and CO2 sorption analyses suggest that the material possesses remarkably high microporosity (SBET=1236 m2 g−1; CO2 uptake=3.5 mmol g−1 at 1 bar and 0 °C). The compound also shows selective adsorption behavior for Cu2+ over Co2+ and Ni2+ ions." @default.
• W1884662242 created "2016-06-24" @default.
• W1884662242 creator A5034788797 @default.
• W1884662242 creator A5078609774 @default.
• W1884662242 creator A5085554982 @default.
• W1884662242 creator A5091881096 @default.
• W1884662242 date "2015-12-01" @default.
• W1884662242 modified "2023-09-23" @default.
• W1884662242 title "Gas sorption and transition-metal cation separation with a thienothiophene based zirconium metal–organic framework" @default.
• W1884662242 cites W1964451037 @default.
• W1884662242 cites W1967538420 @default.
• W1884662242 cites W1967812076 @default.
• W1884662242 cites W1976431616 @default.
• W1884662242 cites W1978003458 @default.
• W1884662242 cites W1981903321 @default.
• W1884662242 cites W1985241939 @default.
• W1884662242 cites W1986238480 @default.
• W1884662242 cites W1986614913 @default.
• W1884662242 cites W1988391334 @default.
• W1884662242 cites W1992861508 @default.
• W1884662242 cites W1995116757 @default.
• W1884662242 cites W1996742693 @default.
• W1884662242 cites W1999908724 @default.
• W1884662242 cites W1999918445 @default.
• W1884662242 cites W1999937609 @default.
• W1884662242 cites W2000896218 @default.
• W1884662242 cites W2001283055 @default.
• W1884662242 cites W2002319969 @default.
• W1884662242 cites W2002799357 @default.
• W1884662242 cites W2004550299 @default.
• W1884662242 cites W2005154776 @default.
• W1884662242 cites W2006858659 @default.
• W1884662242 cites W2009741498 @default.
• W1884662242 cites W2015357922 @default.
• W1884662242 cites W2015774245 @default.
• W1884662242 cites W2021523927 @default.
• W1884662242 cites W2022167379 @default.
• W1884662242 cites W2032549515 @default.
• W1884662242 cites W2033058098 @default.
• W1884662242 cites W2033191016 @default.
• W1884662242 cites W2042782088 @default.
• W1884662242 cites W2044369290 @default.
• W1884662242 cites W2046690462 @default.
• W1884662242 cites W2047198066 @default.
• W1884662242 cites W2047551948 @default.
• W1884662242 cites W2054606833 @default.
• W1884662242 cites W2056383280 @default.
• W1884662242 cites W2056570035 @default.
• W1884662242 cites W2057266864 @default.
• W1884662242 cites W2058459839 @default.
• W1884662242 cites W2062269633 @default.
• W1884662242 cites W2063886231 @default.
• W1884662242 cites W2066130908 @default.
• W1884662242 cites W2070178225 @default.
• W1884662242 cites W2071051228 @default.
• W1884662242 cites W2075535386 @default.
• W1884662242 cites W2075669271 @default.
• W1884662242 cites W2077755071 @default.
• W1884662242 cites W2079808548 @default.
• W1884662242 cites W2091071755 @default.
• W1884662242 cites W2091648094 @default.
• W1884662242 cites W2091999956 @default.
• W1884662242 cites W2094145140 @default.
• W1884662242 cites W2097595950 @default.
• W1884662242 cites W2098032582 @default.
• W1884662242 cites W2099486431 @default.
• W1884662242 cites W2100852443 @default.
• W1884662242 cites W2102312674 @default.
• W1884662242 cites W2111846617 @default.
• W1884662242 cites W2115764422 @default.
• W1884662242 cites W2115960399 @default.
• W1884662242 cites W2121614603 @default.
• W1884662242 cites W2129933386 @default.
• W1884662242 cites W2131620931 @default.
• W1884662242 cites W2132214249 @default.
• W1884662242 cites W2138078544 @default.
• W1884662242 cites W2138953685 @default.
• W1884662242 cites W2142268163 @default.
• W1884662242 cites W2142807751 @default.
• W1884662242 cites W2149092224 @default.
• W1884662242 cites W2153906458 @default.
• W1884662242 cites W2314500080 @default.
• W1884662242 cites W2316754777 @default.
• W1884662242 cites W2321539073 @default.
• W1884662242 cites W2322456100 @default.
• W1884662242 cites W2322759533 @default.
• W1884662242 cites W2323189487 @default.
• W1884662242 cites W2324194052 @default.
• W1884662242 cites W2326895271 @default.
• W1884662242 cites W2858547974 @default.
• W1884662242 cites W2950793961 @default.
• W1884662242 cites W4205576597 @default.
• W1884662242 doi "https://doi.org/10.1016/j.jssc.2015.09.034" @default.
• W1884662242 hasPublicationYear "2015" @default.
• W1884662242 type Work @default.
• W1884662242 sameAs 1884662242 @default.
• W1884662242 citedByCount "15" @default.
• W1884662242 countsByYear W18846622422016 @default.

• next