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• W1885753003 endingPage "6600" @default.
• W1885753003 startingPage "6584" @default.
• W1885753003 abstract "Abstract A stereocontrolled synthesis of epoxide 6 , which represents the C n –C n +7 or “eastern moiety” building block for the title compounds, has been realized in 19 steps. Our synthesis started from tetrabromoacetone 26 and afforded dibromotriene 33b in six steps. The latter was subjected to a ring‐closing metathesis, which gave the dibromovinyl‐substituted lactone 34 in high yield. A highly stereoselective conjugate addition/enolate aldolization sequence established the additional stereocenters with perfect selectivity. Epoxide 47b was reached in another eight steps, which included a C–SiMe 2 Ph → C–OH oxidation in the presence of an acetal group. The final structure 6 was completed by hydrostannylation/brominolysis." @default.
• W1885753003 created "2016-06-24" @default.
• W1885753003 creator A5007065175 @default.
• W1885753003 creator A5032839055 @default.
• W1885753003 date "2013-09-17" @default.
• W1885753003 modified "2023-10-10" @default.
• W1885753003 title "Stereocontrolled Synthesis of a C<i>ⁿ</i>-C<i>ⁿ</i>⁺⁷Building Block (“Eastern Moiety”) for the Unnatural Enantiomers of Important Polyol,Polyene Antibiotics Based on a Ring-Closing Metathesis and an Aldol Addition of a Lactone Enolate" @default.
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