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- W1887292273 abstract "Mössbauer spectroscopy, magnetic susceptibility and optical absorption studies have been carried out in order to investigate the states of iron ions in ZrF 4 -based fluoride glasses prepared using oxidising (NF 3 and O 2 ) and inert (Ar) atmospheres. Under oxidising atmospheres iron ions are present as high-spin ferric ions in an octahedral field, while under an inert atmosphere they are in high-spin ferrous states, occupying two inequivalent octahedral sites. In addition, the behavior of ferric ions under the inert atmosphere has been investigated. Ferric-ion stably exists in Ar, but with the presence of moisture they react with OH and are accordingly reduced to ferrous ions." @default.
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- W1887292273 date "1986-12-01" @default.
- W1887292273 modified "2023-09-29" @default.
- W1887292273 title "Iron Ions in ZrF<sub>4</sub>-Based Fluoride Glasses" @default.
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- W1887292273 doi "https://doi.org/10.1143/jjap.25.1800" @default.
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