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• W188839125 abstract "Several physicochemical properties were experimentally examined for calcium bis(2-ethylhexyl)phosphate (Ca(DEHP)2)/water/n-hexane/calcium chloride systems and compared with sodium bis(2-ethylhexyl)phosphate (NaDEHP)/water/n-hexane/sodium chloride systems in the Winsor II regime to elucidate the effect of changing counter-ion species on the properties of a microemulsion in the amphiphile-concentrated region characterized by the presence of a network-like structure formed from worm-like molecular assemblies. The measurements of small angle X-ray scattering, shear viscosity, electroconductivity were consistently interpreted in terms of the strong tendency of molecular assemblies to become more elongated for Ca2+ than for Na+. The dependence of the dynamical correlation length on the volume fraction of molecular assembly obtained from the dynamic light scattering implies that the freely mobile part in the Ca(DEHP)2 micoemulsion network would be determined by the individual micromechanical property of the worm-like molecular assembly, being different from that in NaDEHP systems determined by the network mesh which becomes more confined with the increase in the volume fraction of the molecular assembly." @default.
• W188839125 created "2016-06-24" @default.
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• W188839125 date "1999-03-01" @default.
• W188839125 modified "2023-10-16" @default.
• W188839125 title "Structure and properties of bis(2-ethyhexyl)phospheric acid microemulsions with a network structure" @default.
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• W188839125 doi "https://doi.org/10.1016/s0927-7757(98)00773-0" @default.
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