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- W1888643352 abstract "Epoxy resins are, due to their excellent properties (such aschemical resistance, dimensional stability, and heatresistence), widely used in practice. The basic principle ofcuring epoxy resins with a hardener containing multiple aminogroups is the crosslinking reaction between active hydrogenatoms in the hardener and the oxirane groups in the epoxyresin. This study deals with the synthesis and characterizationof hexachloro-cyclo-triphosphazene derivative and itssubsequent use for curing epoxy resins. The new hardener wasprepared from hexachloro-cyclo-triphosphazene by nucleophilicsubstitution with isophorone diamine and its curing capabilitywas compared with original isophorone diamine. The preparedderivative hexaisophorone diamino-cyclo-triphosphazene (HICTP)provided advantages over conventional curing system, as itimproved mechanical properties as well as the flame resistance.Testing of the cured epoxy resin during burning was carried outusing dual cone calorimeter, which enables more extensivemonitoring of parameters in comparison with testing usingoxygen index that has been used in many publications. The epoxyresin cured with the prepared phosphorus containing HICTPexhibits lower values for total heat release, amount of smokereleased and oxygen consumed, which may cause a slower flamespread. (C) 2015 Wiley Periodicals, Inc." @default.
- W1888643352 created "2016-06-24" @default.
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- W1888643352 date "2015-10-01" @default.
- W1888643352 modified "2023-09-28" @default.
- W1888643352 title "Synthesis of curing agent for epoxy resin based on halogenophosphazene" @default.
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- W1888643352 doi "https://doi.org/10.1002/app.42917" @default.
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