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- W1889590400 abstract "Layered copper-nickel cyanide, CuNi(CN)4, a 2-D negative thermal expansion material, is one of a series of copper(ii)-containing cyanides derived from Ni(CN)2. In CuNi(CN)4, unlike in Ni(CN)2, the cyanide groups are ordered generating square-planar Ni(CN)4 and Cu(NC)4 units. The adoption of square-planar geometry by Cu(ii) in an extended solid is very unusual." @default.
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- W1889590400 date "2015-01-01" @default.
- W1889590400 modified "2023-10-02" @default.
- W1889590400 title "Chemistry and structure by design: ordered CuNi(CN)<sub>4</sub> sheets with copper(<scp>ii</scp>) in a square-planar environment" @default.
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- W1889590400 doi "https://doi.org/10.1039/c5dt01127b" @default.
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