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- W1892029078 abstract "The temperature dependence of the cyclization ratio of the free radical cyclopolymerization of methacrylic anhydride in chloroform solutions was investigated. The experimental difference between the activation entropy of the intramolecular cyclization and the activation entropy of the intermolecular addition of the growing chain radical onto a monomer molecule was found to agree satisfactorily with the difference calculated on the basis of a semiempirical method. It came out that, even in the present case, the intramolecular cyclizations are favoured over the intermolecular additions by a smaller entropy decrease." @default.
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- W1892029078 date "1977-01-01" @default.
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- W1892029078 doi "https://doi.org/10.1002/macp.1977.021780113" @default.
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