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• W1892122938 endingPage "1120" @default.
• W1892122938 startingPage "1113" @default.
• W1892122938 abstract "The influence of composition on Fe2+-Mg intracrystalline distribution was studied in eleven synthetic crystals belonging to the spinel (sensu stricto)-hercynite series (Mg1-yFe2+y)Al2O4, with 0 ≤ y ≤ 1, produced by flux-growth at 800 °C. Samples were analyzed by single-crystal X-ray diffraction and electron microprobe methods, and found to be chemically homogeneous with only minor Fe3+, which substitutes for Al and increases up to 0.09 atoms per formula unit with total Fe. Structural parameters a, u, T-O, and M-O increase with hercynite content and, among bond distances, T-O shows the maximum change, from 1.920 to 1.968 Å. The a variation from 8.0855 to 8.1646 Å is essentially caused by the T-O increase that, in turn, is due to the cooperative effects of (1) Fe2+ → Mg substitution and (2) decrease of inversion from 0.23 to 0.15 along the series." @default.
• W1892122938 created "2016-06-24" @default.
• W1892122938 creator A5079534133 @default.
• W1892122938 creator A5080670101 @default.
• W1892122938 date "2002-08-01" @default.
• W1892122938 modified "2023-10-16" @default.
• W1892122938 title "Intersite distribution of Fe²⁺and Mg in the spinel (sensu stricto)–hercynite series by single-crystal X-ray diffraction" @default.
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• W1892122938 doi "https://doi.org/10.2138/am-2002-8-908" @default.
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