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- W1893868081 abstract "The optical properties of a thin film of the [Ru(bpy)3][NaCr(ox)3] network structure obtained by pulsed laser deposition are described. The luminescence shows the characteristic doublet of R lines at 14400cm−1 of the spin-forbidden ligand field transition E2(t2g3)→A24(t2g3) of the [Cr(ox)3]3− chromophore. The resonant energy migration within the R1 line shows that the three-dimensional crystallographic structure is preserved during the coating process. The observation of the R lines of [Cr(bpy)3]3+ at 13710cm−1 indicates that a small fraction of Cr3+ ions migrate from the oxalate network to the tris-bipyridine cation site in the cavities of the network." @default.
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- W1893868081 date "2005-12-12" @default.
- W1893868081 modified "2023-09-24" @default.
- W1893868081 title "Optical properties of thin films of [Ru(bpy)3][NaCr(ox)3] polymeric networks" @default.
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