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- W1895918679 abstract "Abstract Two different types of fluxes, namely sodium based and chloride based fluxes were used to grow Cr substituted barium and strontium hexaferrite ferrite crystals, (Sr,Ba)Fe 12 − x Cr x O 19 at comparatively low temperatures of about 1300 °C. The sodium based flux led to growth of larger crystals up to 5 mm, but with only minor Cr contents x ≤ 0.07. From the chloride based flux the obtained Cr contents are significantly higher with x = 5.7 (Sr) and x = 3.4 (Ba), however, crystals reach only sizes in the sub-mm range. X-ray absorption spectroscopy data support exclusively isovalent substitution of Fe 3+ by Cr 3+ even for very low Cr contents. 57 Fe Mosbauer spectroscopy reveals Cr to preferentially occupy the six-fold by oxygen coordinated site at 12 k and, to a lower degree, 2 a and 4 f 2 in space group P 6 3 / mmc . All characteristic magnetic properties drop upon Cr substitution, e. g., the Curie temperature from 728 K for pure BaFe 12 O 19 to 465 K for BaFe 8.6 Cr 3.4 O 19 , the saturation magnetization from 71 emu/g to 29.7 emu/g and the coercive field from 363 Oe to 45 Oe." @default.
- W1895918679 created "2016-06-24" @default.
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- W1895918679 date "2015-12-01" @default.
- W1895918679 modified "2023-09-26" @default.
- W1895918679 title "Single crystal growth, structural characteristics and magnetic properties of chromium substituted M-type ferrites" @default.
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- W1895918679 doi "https://doi.org/10.1016/j.solidstatesciences.2015.10.005" @default.
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