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• W1896478660 abstract "Abstract The syntheses and physicochemical properties of the three dinitrogen complexes [Mo(N 2 ) 2 (tdppme)(PMe 3 )], [Mo(N 2 )(tdppme)(PMe 3 ) 2 ] and [Mo(N 2 ) 2 (tdppme)(PMe 2 Ph)] supported by the tripodal ligand 1,1,1‐tris(diphenylphosphinomethyl)ethane (tdppme) are reported. The complexes are characterized by 31 P NMR‐, IR‐ and Raman spectroscopy. The influence of the ligand tdppme on the coordination of PMe 3 , PMe 2 Ph, PMePh 2 , PPh 3 and dcpm (bis(dicyclohexylphosphine) is investigated and compared to earlier results involving dppm and dmpm as co‐ligands." @default.
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• W1896478660 date "2014-10-06" @default.
• W1896478660 modified "2023-09-26" @default.
• W1896478660 title "Molybdenum(0)-N₂Complexes Supported by the Tripod Ligand 1,1,1-Tris(Diphenyl-Phosphinomethyl)Ethane: Steric Influence on the Coordination of Mono- and Diphosphine Coligands" @default.
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• W1896478660 doi "https://doi.org/10.1002/zaac.201400358" @default.
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