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• W1897301988 abstract "The DNA-binding behaviors of two aliphatic polyamine Ru(II) complexes, [Ru(dppt)(dien)](ClO4)2 (1) and [Ru(pta)(dien)](ClO4)2 (2) (dppt, pta, and dien standing for 3-(1,10-phenanthrolin-2-yl)-5,6-diphenyl-as-triazine, 3-(1,10-phenanthrolin-2-yl)-5,6-diphenyl-as-triazino[5,6-f]-acenaphthylene, and diethylenetriamine, respectively), were studied through absorption titration, thermal denaturation, and viscosity measurements. The results indicate that the DNA-binding affinity of 2 is much greater than that of 1; 2 binds to CT-DNA in an intercalative mode but 1 binds to CT-DNA through partial intercalation. In addition, the complexes react with DNA in an energy-driven process with a decrease in entropy. The photocleavage of plasmid pBR322 can be triggered by 1 and 2 and strengthened with an increased concentration of both complexes. The scavenging activity of 1 against hydroxyl radical (˙OH) is slightly better than that of 2 according to the antioxidation experiment. The standard cytotoxicity experiments were ..." @default.
• W1897301988 created "2016-06-24" @default.
• W1897301988 creator A5025565506 @default.
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• W1897301988 date "2015-09-24" @default.
• W1897301988 modified "2023-09-24" @default.
• W1897301988 title "Aliphatic polyamine ruthenium(II) complexes: crystal structure, DNA-binding, photocleavage, cytotoxicity, and antioxidation" @default.
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• W1897301988 doi "https://doi.org/10.1080/00958972.2015.1088527" @default.
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