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- W1899576306 abstract "Addition of sodium chloride and some surface active agents to the micellar or reverse-micellar solution of sodium alkyl 2-hydroxy-3-methacryloyloxypropyl phosphates (Cn-AHMP) surprisingly changed the ability of spontaneous polymerization. Low-reactive C8AHMP in water became spontaneously polymerizable upon addition of NaCl to achieve a conversion of ca. 100%, and the non-reactive C16-AHMP turned out to be highly reactive upon addition of an equimolar amount of sodium dodecyl glyceryl phosphate in water and in benzene. On the other hand, the high reactivity of C12-AHMP decreased upon addition of the surfactants. These results indicate that the additives modify the monomer aggregation state, and that there is a state of aggregation that is most suitable to generate the initiating radical species. The NMR measurement of the proton spin relaxation time gave important information on the aggregation state. In the spontaneous copolymerization of C12- and C14-AHMP in water, the total conversion decreased with increasing feed content of the C14 monomer, but the residual monomer ratios were equal to the initial ones. ESR spectra were detected directly in the spontaneous polymerization system of C12-AHMP in both water and benzene. The polymerization of C16-AHMP initiated with a pre-polymerized solution of C12-AHMP showed that some portion of the polymer radicals remained active for 2 − 3 h at room temperature, after the first-stage polymerization of C12-AHMP was complete." @default.
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- W1899576306 date "1993-06-01" @default.
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- W1899576306 doi "https://doi.org/10.1002/macp.1993.021940609" @default.
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