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- W190027150 abstract "The emission spectrum of VN has been investigated in the 3400–19 400 cm−1 region using a Fourier transform spectrometer. The bands were observed from the reaction of VOCl3 vapor with active nitrogen. In addition to the previously known transitions of VN, several new bands observed in the visible and near infrared have been classified into two new electronic transitions, e1Π–a1Δ and d1Σ+–b1Σ+. Four bands with origins near 5267.49, 5290.48, 5318.86, and 5349.45 cm−1 have been identified as the 0–0, 1–1, 2–2, and 3–3 bands, respectively, of the d1Σ+–b1Σ+ transition. The excited d1Σ+ state is known from the d1Σ+–X3Δ1 transition observed previously by B. Simard, C. Masoni, and P. A. Hackett (J. Mol. Spectrosc.136, 44–55 (1989)). The d1Σ+–X3Δ1 transition has also been observed in our spectra. Another band with two P, two Q, and two R branches and band origin near 14 292.77 cm−1 has been assigned as the e1Π–a1Δ transition. A rotational analysis of bands of the three transitions has been carried out and the spectroscopic constants have been evaluated. The principal spectroscopic constants for the a1Δ state, which is most probably the lowest singlet state of VN, are B0=0.634 804(31) cm−1, D0=9.03(14)×107 cm−1, and r0=1.554 891(38) Å, while the equilibrium rotational constants for the b1Σ+ state are Be=0.617 896(26) cm−1, αe=0.004 148(19) cm−1, and re=1.576 022(33) Å. The d1Σ+ state is affected by interactions with a close-lying perturbing state." @default.
- W190027150 created "2016-06-24" @default.
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- W190027150 date "2001-11-01" @default.
- W190027150 modified "2023-10-16" @default.
- W190027150 title "Emission Spectroscopy of the d1Σ+–b1Σ+, d1Σ+–X3Δ1, and e1Π–a1Δ Systems of VN" @default.
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- W190027150 doi "https://doi.org/10.1006/jmsp.2001.8436" @default.
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