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- W1900894998 abstract "Abstract Single crystals of Ca 2 Ga 2 O 5 have been synthezised in a piston cylinder apparatus at 1250°C/2.5 GPa from precursors prepared by solid state reactions. The crystal structure has been investigated by X-ray diffraction methods. The compound crystallizes in the orthorhombic space group I 2 mb ( a = 5.3525(1)Å, b = 14.6666(1)Å, c = 5.5651(1)Å, V = 436.88(1)Å 3 , Z = 4, D calc =4.56 g cm -3 and is isotypic with Ca 2 FeAlO 5 (Brownmillerite) and Ca 2 Al 2 O 5 . Basic building units of Ca 2 Ga 2 O 5 are (1) layers of perovskite type corner connected GaO 6 -octahedra and (2) sheets comprised of zweier single chains of GaO 4 -tetrahedra. The alternate stacking of the two building units results in a threedimensional framework in which the calcium cations are incorporated for charge compensation. Dicalcium gallate is the first structurally characterized representative of a double oxide in the system CaO - Ga 2 O 3 showing a sixfold coordination of Ga 3+ ." @default.
- W1900894998 created "2016-06-24" @default.
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- W1900894998 date "2001-04-01" @default.
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- W1900894998 title "Ca<sub>2</sub>Ga<sub>2</sub>O<sub>5</sub>: a new high pressure oxogallate" @default.
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- W1900894998 doi "https://doi.org/10.1524/zkri.216.4.206.23257" @default.
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