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- W1901517067 abstract "A general method to synthesize functionalized allyl α-amino acid derivatives through an irreversible oxy-2-azonia-Cope rearrangement is reported. In the presence of AlCl3, the reaction of imino ethyl glyoxalates with various β,γ-unsaturated ketones furnished the corresponding allyl α-amino acid derivatives. The key to the success of this method is the amide bond formation, which makes the rearrangement irreversible. This reaction system constitutes a new strategy for the synthesis of unusual allyl glycine derivatives, which are valuable synthetic intermediates. An efficient and operationally simple three-component version of this reaction was also performed." @default.
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- W1901517067 date "2014-02-06" @default.
- W1901517067 modified "2023-10-09" @default.
- W1901517067 title "Irreversible Oxy-2-azonia-Cope Rearrangements for the Synthesis of Functionalized Allyl α-Amino Acid Derivatives" @default.
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- W1901517067 doi "https://doi.org/10.1002/ejoc.201301818" @default.
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