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- W1901697788 abstract "Stable hemiaminals can be obtained in the one-pot reaction between 2-aminopyrimidine and nitrobenzaldehyde derivatives. Ten new hemiaminals have been obtained, six of them in crystal state. The molecular stability of these intermediates results from the presence of both electron-withdrawing nitro groups as substituents on the phenyl ring and pyrimidine ring, so no further stabilisation by intramolecular interaction is required. Hemiaminal molecules possess a tetrahedral carbon atom constituting a stereogenic centre. As the result of crystallisation in centrosymmetric space groups both enantiomers are present in the crystal structure." @default.
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- W1901697788 date "2015-08-06" @default.
- W1901697788 modified "2023-10-18" @default.
- W1901697788 title "Stable Hemiaminals: 2-Aminopyrimidine Derivatives" @default.
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- W1901697788 doi "https://doi.org/10.3390/molecules200814365" @default.
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