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- W1902707786 abstract "Sol-gel transition of gelatin was analyzed as a multisite stoichiometric reaction of a gelatin molecule with water and solute molecules. The equilibrium sol-gel transition temperature, Tt , was estimated from the average of gelation and melting temperature measured by differential scanning calorimetry. From Tt and the melting enthalpy, ΔHsol , the equilibrium sol-to-gel ratio was estimated by the van't Hoff equation. The reciprocal form of the Wyman-Tanford equation, which describes the sol-to-gel ratio as a function of water activity, was successfully applied to obtain a good linear relationship. From this analysis, the role of water activity on the sol-gel transition of gelatin was clearly explained and the contributions of hydration and solute binding to gelatin molecules were separately discussed in sol-gel transition. The general solution for the free energy for gel-stabilization in various solutions was obtained as a simple function of solute concentration." @default.
- W1902707786 created "2016-06-24" @default.
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- W1902707786 date "2015-09-24" @default.
- W1902707786 modified "2023-10-18" @default.
- W1902707786 title "Thermodynamic analysis of sol-gel transition of gelatin in terms of water activity in various solutions" @default.
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- W1902707786 doi "https://doi.org/10.1002/bip.22706" @default.
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