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- W1905733117 abstract "[205815-80-1] C46H61MoNO2, (MW 755.92)C42H53MoNO2, (MW 699.82)C76H93MoNO3, (MW 1164.50)InChI = 1S/C24H34O2.C12H17N.C10H12.Mo/c1-13-11-17(23(5,6)7)21(25)19(15(13)3)20-16(4)14(2)12-18(22(20)26)24(8,9)10;1-8(2)10-6-5-7-11(9(3)4)12(10)13;1-10(2,3)9-7-5-4-6-8-9;/h11-12,25-26H,1-10H3;5-9H,1-4H3;1,4-8H,2-3H3;/q;;;+2/p-2InChIKey = YLWIQLXPHIAIEN-UHFFFAOYSA-L(chiral Mo-centered alkylidene catalyst for asymmetric ring-clos-ing, ring-opening, and cross metathesis)Solubility: soluble in diethyl ether, benzene, n-pentane, dichloro-methane, and most organic solvents.Form Supplied in: dark red crystals. Racemic catalyst is supplied as an orange powder.Purification: recrystallized under an inert atmosphere from n-pentane at −30 °C. The n-pentane is generally made ‘olefin’ free by stirring over sulfuric acid repeatedly until the acid no longer discolors, followed by distillation and degassing.Handling, Storage, and Precautions: air and moisture sensitive. The catalyst should be stored at or below −20 °C and under an inert atmosphere. Solvents should be distilled and degassed prior to use. For long-term storage, the catalyst must be kept in the solid state to avoid decomposition." @default.
- W1905733117 created "2016-06-24" @default.
- W1905733117 creator A5081485832 @default.
- W1905733117 date "2003-04-15" @default.
- W1905733117 modified "2023-09-27" @default.
- W1905733117 title "[(1S)-3,3′-bis(1,1-dimethylethyl)-5,5′,6,6′-tetramethyl[1,1′-biphenyl]-2,2′-diolato(2-)-O,O′][2,5-bis(1-methylethyl)benzenaminato(2-)](2-methyl-2-phenylpropylidene)molybdenum [(S)-Schrock-Hoveyda catalyst]" @default.
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- W1905733117 doi "https://doi.org/10.1002/047084289x.rn00106" @default.
- W1905733117 hasPublicationYear "2003" @default.
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