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- W1906788975 abstract "Mn(II), Co(II), Ni(II) and Cu(II) complexes of the β -ketoimine, [(C 6 H 5 )C:OCH:C(CH 3 )NH(C 6 H 7 N 2 )], and their mixed complexes with 2,2′ -dipyridine (bipy) and 1,10-phenanthroline (phen) are synthesized. The ligand, though containing four donor atoms, was bidentate, coordinating with O and imine N. 1 Hnmr reveals that the ligand exists, predominantly, as ketoimine in polar solvent, but as enolimine in the solid state. All complexes were characterized by microanalyses, magnetic susceptibility, conductance, infrared, and electronic spectral measurements. Spectroscopic and magnetic data are consistent with the adoption of tetrahedral geometry to the Mn(II) and Ni(II) and square planar for Cu(II) complexes while the Co(II) complex and the adducts are octahedral. All the complexes are high-spin, and are non-electrolyte in nitromethane. The compounds exhibited activities against four Gram negative bacilli (Proteus sp, Klebsiella sp, Pseudomonas sp and Salmonella spp); three Gram positive organisms (B. s..." @default.
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- W1906788975 date "2009-04-03" @default.
- W1906788975 modified "2023-10-16" @default.
- W1906788975 title "Spectroscopic, Magnetic and Biological Studies on Some Metal(II) Complexes of 3-(4,6-Dimethyl-2Pyrimidinylamino)-1-Phenyl-2-Butenone and the Mixed Complexes with 2,2′ -Bipyridine and 1,10-Phenanthroline" @default.
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- W1906788975 doi "https://doi.org/10.1080/15533170902785109" @default.
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