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• W1906861067 abstract "H2O3PCH2NH2+CH2PO3H− was hydrothermally reacted with Cu(II) in aqueous solution at a 1 : 1 ratio, forming Cu3[NH2(CH2PO3)2]2 (1). Two kinds of coordination environments exist around the central copper ions: a distorted square planar Cu(1) ion and an octahedral Cu(2) ion. They are bridged with one terminal oxygen atom forming a 3D-coordination framework of layers sharing corners. Novel antiferromagnetic coupling between the two kinds of Cu units was observed at 15 K, followed by ferromagnetic ordering at 9 K." @default.
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• W1906861067 date "2003-01-01" @default.
• W1906861067 modified "2023-10-09" @default.
• W1906861067 title "A novel copper organophosphonate with a pore-like 3D framework and Cu–Cu magnetic ordering" @default.
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• W1906861067 doi "https://doi.org/10.1039/b304610a" @default.
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